When does Pearl enter Valorant's Competitive queue?

Pearl is the latest map in Valorant and will be available in the Competitive queue tomorrow. It went live with Patch 5.0 on June 22, with the launch of the new Episode.

Valorant Maps In-depth Guide

VALORANT Patch Notes 5.0

Valorant Episode 5 ”Dimension”, featuring new map ”Pearl”, available for free from June 22

Valorant Episode 5 Act 3: Release Date, New Content, Battle Pass, New Agent and More

Valorant Pearl Map - Release Date, Sites, Layout and more - GINX TV

Is pearl so unlikeable that everyone leaves the deathmatch? So i had my fun with my knife i blew the bank on : r/VALORANT

A professional VALORANT analyst's guide to playing Pearl - Upcomer

When Is Pearl Being Added To Ranked In Valorant?

Is Pearl in the unrated queue? : r/VALORANT

Valorant Patch 5.0 Unveils New Rank Between Diamond and Immortal

A professional VALORANT analyst's guide to playing Pearl - Upcomer

When will Valorant Episode 5 Act 2 Competitive Queue end for all regions?

Patch Notes/4.0, Valorant Wiki